A novel combined system using Na2S2O8/urea to simultaneously remove SO2 and NO in marine diesel engine exhaust

Abstract

The novel combined system using Na₂S₂O₈/urea was used to simultaneously absorb nitric oxide and sulfur dioxide emissions from marine diesel engines as well as inhibit the formation of nitrate in cleaning wastewater to meet the increasingly stringent requirements of regulations. The influences of reaction temperature, Na₂S₂O₈ concentration, urea concentration, SO₂ concentration, NO concentration and pH value on SO₂ removal efficiency, NO removal efficiency and nitrate concentration were investigated. The experimental results showed that different reaction temperatures had different influences on SO₂ removal efficiency, NO removal efficiency and nitrate concentration. An increase in Na₂S₂O₈ could improve the absorption of NO. The addition of urea could effectively improve the removal efficiency of NO and reduce the nitrate concentration. The removal efficiencies of 1000 ppm NO and 1000 ppm SO₂ achieved 100 % with 0.2 mol/L Na₂S₂O₈ and 2 mol/L urea at 70℃, and the nitrate content was 8.56 mg/L which was far lower than the regulatory requirement of 60 mg/L. The acidic condition (pH ≤ 5.5) not only facilitated the absorption of NO but also reduced the generation of nitrate. According to the experimental results, the novel combined system was promising to be applied to the control technology of marine diesel engine exhaust.

Keywords: Marine diesel engine exhaust; NO; Na(2)S(2)O(8); SO(2); Urea.