Improving the energy storage density of dielectrics without sacrificing charge-discharge energy storage efficiency and reliability is crucial to the performance improvement of modern electrical and electronic systems, but traditional methods of doping high-dielectric ceramics cannot achieve high energy storage densities without sacrificing reliability and storage efficiency. Here, an all-organic energy storage dielectric composed of ferroelectric and linear polymer with a sandwich structure is proposed and successfully prepared by the electrostatic spinning method. Additionally, the effect of the ferroelectric/linear volume ratio on the dielectric properties, breakdown, and energy storage is systematically studied. The results show that the structure has good energy storage characteristics with a high energy storage density (9.7 J/cm3) and a high energy storage efficiency (78%). In addition, the energy storage density of the composite dielectric under high energy storage efficiency (90%) is effectively improved (25%). This result provides theoretical analysis and experience for the preparation of multilayer energy storage dielectrics which will promote the development and application of energy storage dielectrics.
Keywords: P(VDF-TrFE-CFE); PMMA; energy storage efficiency; sandwich structure.