Stress or Strain Does Not Impact Sorption in Stiff Mesoporous Materials

Langmuir. 2020 Sep 22;36(37):11054-11060. doi: 10.1021/acs.langmuir.0c01939. Epub 2020 Sep 9.

Abstract

The present paper investigates strain-induced sorption in mesoporous silicon. Contrarily to a previous report based on indirect evidence, we find that external mechanical strain or stress has no measurable impact on sorption isotherms, down to a relative accuracy of 10-3. This conclusion is in agreement with the analysis of the sorption-induced strain of porous silicon and holds for other stiff mesoporous materials such as porous silicas.