We demonstrate the thermal bleaching effect on a photodarkened thulium-doped fiber (TDF) in detail. The bleaching effect on visible transmission initiates at 250 °C and a complete recovery is achieved at 550 °C. Prior to the recovery, a post-irradiation heat-induced spectral loss is observed. It indicates that an intermediate energy state is generated in the TDF under exposure to near-infrared (NIR) radiation, exhibiting the spectral attenuation in visible (VIS) and NIR region as driven by color center after thermal activation. And, with thermal treatment, the bleached TDF shows a partial photodarkening (PD) resistance when it is subject to photoirradiation again. In addition, the temperature-dependent spectral broadening and red shift that may distort the measured decay curve of excess loss is observed and discussed.