A new technique is developed for reconstructing the temperature and species-concentration fields by employing tunable diode laser absorption spectroscopy (TDLAS) and laser-induced breakdown spectroscopy (LIBS) on axisymmetric combustion fields. For two-line thermometry, the uncertainties in linestrengths of the absorption lines may cause systematic errors in temperature and species concentration estimations. Thus, the radial profiles of water vapor concentration are obtained first using the LIBS, assuming that the combustion is complete; then, the radial temperature profiles are estimated from the radial profiles of absorption coefficient, as reconstructed from the absorbance profiles obtained using the TDLAS. The spectral lines of water vapor at 7185.6 and 7444.36 cm-1 are selected as the linestrengths show monotonic decreases with the increase in temperature within the measuring temperature range. The radial profiles of temperature and water mole fraction are well-reconstructed, and the measurement error is found to be as low as 3%. The technique yielded higher temperatures compared to the thermocouple, possibly owing to the significant radiative heat loss in the thermocouple data.