Green surfactants alkyl glycosides are key to solve the inherent problem of water solubility due to their commercial application and extensive scientific research. Based on the enhancement strategy of hydrophilicity through the reconstruction of the conventional alkyl β-d-maltoside by introducing an oxyethyl group (-OCH2CH2-), d-maltose was used to prepare a series of nonionic disaccharide-based surfactants alkoxyethyl β-d-maltosides (4a-h, n = 6-16) so that the related water solubility was effectively improved, while the corresponding surface activity and other excellent properties were still maintained. Their physicochemical properties, including water solubility, surface activity, moisture absorption, and thermotropic liquid crystalline behavior, were investigated. The liquid crystal texture of alkoxyethyl β-d-maltosides (n = 7-16) has a fan-shaped focal conic texture. Furthermore, decoxyethyl β-d-maltoside had the strongest foaming characteristic and the best foam stability. Moreover, dodecoxyethyl β-d-maltoside (4f, n =12) had stronger emulsifying activity in the rapeseed oil/water system. Finally, CTAC/4f binary surfactants had an obvious synergistic effect. Such β-d-maltosides should have good application prospects in the future.
Keywords: alkoxyethyl β-d-maltoside; binary surfactants; surface activity; thermotropic liquid crystalline; water solubility.