One-Step Synthesis of Spin Crossover Nanoparticles Using Flow Chemistry and Supercritical CO2

Abstract

Switchable materials are increasingly considered for implementation in devices or multifunctional composites leading to a strong need in terms of reliable synthetic productions of well-defined objects. Here, an innovative and robust template-free continuous process was developed to synthesize nanoparticles of a switchable coordination polymer, including the use of supercritical CO₂ , aiming at both quenching the particle growth and drying the powder. This all-in-one process offers a 12-fold size reduction in a few minutes while maintaining the switching properties of the selected spin crossover coordination polymer.

Keywords: flow chemistry; nanoparticles; spin crossover; supercritical CO2.