Complementary Hybrid Semiconducting Superlattices with Multiple Channels and Mutual Stabilization

Nano Lett. 2020 Jul 8;20(7):4864-4871. doi: 10.1021/acs.nanolett.0c00859. Epub 2020 Jun 18.

Abstract

An organic-inorganic hybrid superlattice with near perfect synergistic integration of organic and inorganic constituents was developed to produce properties vastly superior to those of either moiety alone. The complementary hybrid superlattice is composed of multiple quantum wells of 4-mercaptophenol organic monolayers and amorphous ZnO nanolayers. Within the superlattice, multichannel formation was demonstrated at the organic-inorganic interfaces to produce an excellent-performance field effect transistor exhibiting outstanding field-effect mobility with band-like transport and steep subthreshold swing. Furthermore, mutual stabilizations between organic monolayers and ZnO effectively reduced the performance degradation notorious in exclusively organic and ZnO transistors.

Keywords: complementary; hybrid superlattices; multiple channels; mutual stabilization.