Mercury sources in a subterranean spontaneous combustion area

Abstract

Mercury is a toxic, persistent, and mobile contaminant. Coal spontaneous combustion are widely distributed in the world and releases a great deal of Hg. Identifying the burning coal seam is crucial for quickly extinguishing a coalfield fire. Mercury isotopes can be effective for identifying burning coal seams and beneficial for combating coal spontaneous combustion. In this study, Hg isotopic ratios of coal, topsoil, dustfall, sand, coal fire sponges (CFS), and n-topsoil (topsoil near the CFS) from coal fire area No. 9 in the Wuda coalfield were determined using multiple-collector inductively coupled plasma mass spectrometry (MC-ICPMS). Analysis of the correlation coefficients between the δ²⁰²Hg and Hg concentrations and the low-temperature ashes indicate that the higher mineral concentration in coal seam No. 9 not only increases the Hg concentration but also leads to more positive δ²⁰²Hg values compared to those for coal seam No. 10. By analyzing the Hg isotope characterizations in coal seam No. 9 and No. 10, we determined that Hg isotope characterizations can be useful for discriminating different coal seam Hg values in a coalfield. Significant mass-dependent fractionation (MDF) occur in the coal burning. The fractionation effect of burning and absorption process can play a key role in the δ²⁰²Hg more negative of ground surface samples. If Hg isotopes is added, the effect of coal-fire monitoring may be better. In addition, these finding could be used to better understand the transport and cycling of Hg.

Keywords: Coal fire; Extinguish fire engineering; Fractionation; Hg isotopes; Wuda coalfield.