Oxygen vacancy enhancing Fenton-like catalytic oxidation of norfloxacin over prussian blue modified CeO2: Performance and mechanism

Abstract

To develop an efficient heterogeneous Fenton-like catalyst is of great importance for degrading organic pollutants. CeO₂ was selected as the catalyst carrier. Prussian blue (PB) was chose as the iron resource for its sensitivity to H₂O₂ and low toxicity. PB modified CeO₂ composite was successfully fabricated and used for Fenton-like oxidation of norfloxacin (NOR) in this study. The characteristics of the catalysts demonstrated that the doping of PB distorted the lattice locally and increased the surface area of CeO₂ obviously. The XPS analysis also indicated that chemically supported catalysts PB/CeO₂ with more Ce³⁺ was beneficial to Fenton-like catalytic reaction. The degradation tests showed that the PB/CeO₂ significantly enhanced the removal of NOR which indicated a synergistic effect between PB and CeO₂. The reason should be mainly attributed to the synergetic catalysis of H₂O₂ by Fe³⁺/Fe²⁺ and Ce³⁺/Ce⁴⁺ redox couples. At the same time, PB/CeO₂ composite showed well reusability and wide pH value range of 2-9 with fairly low concentration of iron ions. The reaction mechanisms were identified to be OH oxidation and improvement of oxygen vacancies (OVs).

Keywords: CeO(2); Fenton-like; Norfloxacin; Oxygen vacancies; Prussian blue.