N-Aminorhodanine modified chitosan hydrogel for antibacterial and copper ions removal from aqueous solutions

T A Zidan; Ahmed E Abdelhamid; E G Zaki

doi:10.1016/j.ijbiomac.2020.04.180

N-Aminorhodanine modified chitosan hydrogel for antibacterial and copper ions removal from aqueous solutions

Int J Biol Macromol. 2020 Apr 27:S0141-8130(20)33042-7. doi: 10.1016/j.ijbiomac.2020.04.180. Online ahead of print.

Authors

T A Zidan¹, Ahmed E Abdelhamid², E G Zaki³

Affiliations

¹ Department of Polymers and Pigments, National Research Centre, 33 El Buhouth St., Dokki, Giza 12622, Egypt.
² Department of Polymers and Pigments, National Research Centre, 33 El Buhouth St., Dokki, Giza 12622, Egypt. Electronic address: ahmednrc10@gmail.com.
³ Egyptian Petroleum Research Institute, Nasr City, Cairo 11727, Egypt.

PMID: 32353502
DOI: 10.1016/j.ijbiomac.2020.04.180

Abstract

A novel adsorbent based on N-Aminorhodanine modified chitosan hydrogel was synthesized and evaluated for antibacterial and copper ions removal from aqueous systems. N-Aminorhodanine was reacted with glutaraldehyde to yield Schiff base followed by reaction with chitosan to obtain the new hydrogel adsorbent. The new adsorbent was analyzed using FTIR, ¹H NMR, XRD, TGA, HR-SEM and EDX in addition to the swelling behavior. The maximum adsorption capacities of chitosan and modified chitosan for copper ions were 38 and 62.5 mg/g respectively. The adsorption isotherm belongs Freundlich model and pseudo second order kinetics regime. The adsorption was reach to maximum within 15 min for modified chitosan hydrogel while take about 360 min for chitosan. Regeneration of adsorbent showed only 23% decline after 6 cycles which indicate the stability of the new adsorbent and it can be reused several times with good efficiency. N-Aminorhodanine modified chitosan hydrogel showed good activity towards gram positive bacteria.

Keywords: Adsorption; Antibacterial activity; Chitosan; Copper ions removal; Hydrogel; N-Aminorhodanine.