Influence of Carbyne Content on the Mechanical Performance of Nanothick Amorphous Carbon Coatings

Nanomaterials (Basel). 2020 Apr 18;10(4):780. doi: 10.3390/nano10040780.

Abstract

This study concerns the evaluation of the coefficient of friction, at different temperatures, of amorphous carbon thin films, deposited onto nanocrystalline sputtered copper coatings by clean-technology rf magnetron sputtering. The aim is to access the capacity of carbon thin films, with different contents of sp2 and sp1 bonds, to act as a solid lubricant for copper surfaces. Raman spectroscopy revealed that all the as-deposited coatings consist of amorphous carbon with low defect content and decreasing carbyne concentration with increasing thickness. The tribological tests at 25 °C and 200 °C revealed that, for the higher temperature, the 15 nm carbon coating present 0.001 friction coefficients at 2 N load. Overall, the study presents a one-step technology for the greener production of solid lubrication systems for micro- and nano-components, avoiding the environmental impact of lubricants.

Keywords: 2D carbon thin films; nanocrystalline copper coating; sp1 carbon bonds; zero coefficient of friction.