Coalescence-induced droplet jumping on superhydrophobic surfaces have recently received significant attention owing to their potential in a variety of applications. Previous studies demonstrated that the self-jumping process is inherently inefficient, with an energy conversion efficiency η ≤ 6% and dimensionless jumping velocity Vj* ≤ 0.23. To realize a quick removal of droplets, increasing effort has been devoted to breaking the jumping velocity limit and inducing droplets sweeping. In this work, we used superhydrophobic surfaces with an asymmetric V-groove to experimentally achieve an enhanced coalescence-induced jumping velocity Vj* ≈ 0.61, i.e., more than 700% increase in energy conversion efficiency compared with droplets jumping on flat superhydrophobic surfaces, which is the highest efficiency reported thus far. Moreover, the enhanced jumping direction shows a deviation as high as 60° from the substrate normal. The induced in-plane motion is conducive to remove a considerable number of droplets along the sweeping path and significantly increase the speed of droplet removal. Numerical simulation indicated that the jumping enhancement is a joint effect resulting from the impact of the liquid bridge on the corner of the V-groove and the suppression of droplet expansion by the sidewall of the V-groove. The transient variation of the droplet velocity and the driving force of the coalescing droplets on a surface with and without the asymmetric V-groove were revealed and discussed. Furthermore, effects of groove angle, droplet pair positions, and size mismatches on the jumping velocity and direction have been studied. The novel mechanism of simultaneously increasing the coalescence-induced droplet jumping velocity and changing the jumping direction can be further studied to enhance the efficiency of various applications.