Time-energy uncertainty principle for irreversible heat engines

Philos Trans A Math Phys Eng Sci. 2020 May;378(2170):20190171. doi: 10.1098/rsta.2019.0171. Epub 2020 Mar 30.

Abstract

Even though irreversibility is one of the major hallmarks of any real-life process, an actual understanding of irreversible processes remains still mostly semi-empirical. In this paper, we formulate a thermodynamic uncertainty principle for irreversible heat engines operating with an ideal gas as a working medium. In particular, we show that the time needed to run through such an irreversible cycle multiplied by the irreversible work lost in the cycle is bounded from below by an irreducible and process-dependent constant that has the dimension of an action. The constant in question depends on a typical scale of the process and becomes comparable to Planck's constant at the length scale of the order Bohr radius, i.e. the scale that corresponds to the smallest distance on which the ideal gas paradigm realistically applies. This article is part of the theme issue 'Fundamental aspects of nonequilibrium thermodynamics'.

Keywords: gas kinetics; irreversible processes; statistical mechanics; uncertainty relations.