Enhanced Electrical Conductivity and Seebeck Coefficient in PEDOT:PSS via a Two-Step Ionic liquid and NaBH4 Treatment for Organic Thermoelectrics

Jonathan Atoyo; Matthew R Burton; James McGettrick; Matthew J Carnie

doi:10.3390/polym12030559

Enhanced Electrical Conductivity and Seebeck Coefficient in PEDOT:PSS via a Two-Step Ionic liquid and NaBH₄ Treatment for Organic Thermoelectrics

Polymers (Basel). 2020 Mar 3;12(3):559. doi: 10.3390/polym12030559.

Authors

Jonathan Atoyo¹, Matthew R Burton¹, James McGettrick¹, Matthew J Carnie¹

Affiliation

¹ SPECIFIC-IKC, Materials Research Centre, College of Engineering, Swansea University, Bay Campus, Swansea SA1 8EN, UK.

Abstract

A two-step approach of improving the thermoelectric properties of Poly(3,4-ethylenedioxythiophene)poly(4-styrenesulfonate) (PEDOT:PSS) via the addition of the ionic liquid, 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMIM:TFSI) and subsequent reduction with NaBH₄ is presented. The addition of 2.5 v/v% of EMIM:TFSI to PEDOT:PSS increases the electrical conductivity from 3 S·cm^-1 to 1439 S·cm^-1 at 40 °C. An additional post treatment using the reducing agent, NaBH₄, increases the Seebeck coefficient of the film from 11 µV·K^-1 to 30 µV·K^-1 at 40 °C. The combined treatment gives an overall improvement in power factor increase from 0.04 µW·m^-1·K^-2 to 33 µW·m^-1·K^-2 below 140 °C. Raman and XPS measurements show that the increase in PEDOT:PSS conductivity is due to PSS separation from PEDOT and a conformational change of the PEDOT chains from the benzoid to quinoid molecular orientation. The improved Seebeck coefficient is due to a reduction of charge carriers which is evidenced from the UV-VIS depicting the emergence of polarons.

Keywords: PEDOT:PSS thermoelectric; conducting polymers; enhanced power factor; organic thermoelectric.

Abstract

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