Effects of structural vulnerability of flat-sheet membranes on fouling development in continuous submerged membrane bioreactors

Abstract

The relationship between fouling development in a continuous laboratory-scale membrane reactor (MBR/Lab) and the membrane material was investigated using flat-sheet membranes prepared from four materials (polyvinylidene difluoride (PVDF), polyethersulfone, chlorinated polyvinyl chloride, and polytetrafluoroethylene). Further, the characteristics of the suspension liquid in MBR/Lab were compared with those of samples from actual wastewater treatment plants. It was found that, in addition to the membrane material's own characteristics, the structural vulnerability of the membranes had a determining effect on fouling development. The PVDF membrane showed the highest transmembrane pressure during MBR operation and its surface experienced significant damage because of the shearing stress caused by aeration, resulting in the penetration of the membrane by the fouling compounds. The characteristics of suspension liquid in MBR/Lab were almost similar to those in the MBR at a night-soil treatment plant and the aeration tank of a sewage treatment plant.

Keywords: Extracellular polymeric substance (EPS); Flat-sheet membrane; Fouling; Membrane bioreactor (MBR); Membrane material; Membrane module.