Stacked hexagonal prism of Ag@Ni-MOF-1 as functionalized SERS platform through rational integration of catalytic synthesis of dopamine-quinone at physiological pH with a biomimetic route

Chem Commun (Camb). 2020 Mar 10;56(20):3065-3068. doi: 10.1039/c9cc09145a.

Abstract

Herein, a novel stacked hexagonal prism, Ag@Ni-MOF-1, was designed and developed as an integrated SERS platform not only for successfully catalyzing the in situ synthesis of DA-quinone under physiological pH, but also for establishing an approach for specific determination of Cys, an important species in the brain related to Alzheimer's disease (AD).

MeSH terms

  • Benzoquinones / chemical synthesis*
  • Benzoquinones / chemistry
  • Biomimetic Materials / chemistry*
  • Catalysis
  • Cysteine / analysis
  • Dopamine / chemical synthesis*
  • Dopamine / chemistry
  • Humans
  • Hydrogen-Ion Concentration
  • Nickel / chemistry*
  • Organometallic Compounds / chemical synthesis
  • Organometallic Compounds / chemistry*
  • Silver / chemistry*
  • Spectrum Analysis, Raman

Substances

  • Benzoquinones
  • Organometallic Compounds
  • Silver
  • quinone
  • Nickel
  • Cysteine
  • Dopamine