Sensitivity of source apportionment predicted by a Bayesian tracer mixing model to the inclusion of a sediment connectivity index as an informative prior: Illustration using the Kharka catchment (Nepal)

Abstract

Long-chain saturated fatty acid (LCSFA) isotopic composition in tandem with Bayesian isotope mixing models (BIMM) can provide insight into land use-based sediment sources in catchment systems. Apportioning sediment sources robustly, however, requires careful consideration of how additional factors including topography, surface cover and land use practices interact to influence contributions from individual sources. Prior knowledge can be used in BIMM; however, the full capacity of this functionality has not been thoroughly exploited yet in conjunction with sediment fingerprinting. In response, we propose an approach for applying a state-of-the-art BIMM incorporating a sediment connectivity index (SCI) as an informative prior for sediment source apportionment in a highly hydrodynamic catchment in Nepal. A library of LCSFA carbon isotopic composition was constructed for surface soils collected from mixed forest, upland and lowland terraces in the Kharka micro-catchment. δ¹³C values of LCSFA of time-integrated suspended bulk (<2 mm) sediment were depleted by 4‰ compared to the fine (<0.063 mm) sediment fraction. Conventional source apportionment for fine sediment samples without the SCI informative prior suggested that 66% of the sediment is derived from forest soils followed by lowland (19%) and upland (15%) terraces. Incorporation of the SCI as an informative prior in BIMM, however, modified the original source apportionment estimates to 90%, 9% and 1% respectively. The lower contributions from agricultural terraces are explained by landscape complexity comprising small levelled terraces that reduce hillslope-to-channel sediment connectivity. This study demonstrates the sensitivity of BIMM posterior distributions to incorporation of an informative prior based on a SCI. Inclusion of SCI linked to land use and management can provide a more physically-grounded approach to estimating sediment source contributions from biogeochemical tracers, and critically one which generates results better reflecting what makes good environmental sense in the context of land management and visual evidence of sediment mobilisation and delivery.

Keywords: Compound-specific stable isotope (CSSI); Prior information; Sediment connectivity index; Sediment source apportionment; Water erosion.