Spectral deconvolution associated to the Gaussian fit as a tool for the optimization of photovoltaic electrocoagulation applied in the treatment of textile dyes

Aline Raquel Müller Tones; Eduardo Eyng; Cristiane Lionço Zeferino; Samir de Oliveira Ferreira; Alcione Aparecida de Almeida Alves; Márcia Regina Fagundes-Klen; Elizandra Sehn

doi:10.1016/j.scitotenv.2019.136301

Spectral deconvolution associated to the Gaussian fit as a tool for the optimization of photovoltaic electrocoagulation applied in the treatment of textile dyes

Sci Total Environ. 2020 Apr 15:713:136301. doi: 10.1016/j.scitotenv.2019.136301. Epub 2019 Dec 28.

Authors

Aline Raquel Müller Tones¹, Eduardo Eyng², Cristiane Lionço Zeferino³, Samir de Oliveira Ferreira⁴, Alcione Aparecida de Almeida Alves⁵, Márcia Regina Fagundes-Klen⁶, Elizandra Sehn⁷

Affiliations

¹ Federal University of Technology Paraná, AV. Brasil, Parque Independência, 4232, CEP: 85884-000 Medianeira, Paraná, Brazil; Federal University of Fronteira Sul (UFFS), Rua Jocob Reinaldo Haupenthal, 1580, CEP: 97900-000 Cerro Largo, Rio Grande do Sul, Brazil; State University of West Paraná, Department of Chemical Engineering, Rua da Faculdade, 645, CEP: 85903-000 Toledo, Paraná, Brazil. Electronic address: aline.tones@uffs.edu.br.
² Federal University of Technology Paraná, AV. Brasil, Parque Independência, 4232, CEP: 85884-000 Medianeira, Paraná, Brazil. Electronic address: eduardoeyng@utfpr.edu.br.
³ Federal University of Technology Paraná, AV. Brasil, Parque Independência, 4232, CEP: 85884-000 Medianeira, Paraná, Brazil. Electronic address: crislion@hotmail.com.
⁴ Federal University of Technology Paraná, AV. Brasil, Parque Independência, 4232, CEP: 85884-000 Medianeira, Paraná, Brazil. Electronic address: ferreira.samir@gmail.com.
⁵ Federal University of Fronteira Sul (UFFS), Rua Jocob Reinaldo Haupenthal, 1580, CEP: 97900-000 Cerro Largo, Rio Grande do Sul, Brazil. Electronic address: alcione.almeida@uffs.edu.br.
⁶ State University of West Paraná, Department of Chemical Engineering, Rua da Faculdade, 645, CEP: 85903-000 Toledo, Paraná, Brazil. Electronic address: fagundes.klen@gmail.com.
⁷ Federal University of Technology Paraná, AV. Brasil, Parque Independência, 4232, CEP: 85884-000 Medianeira, Paraná, Brazil. Electronic address: elizandrasehn@hotmail.com.

PMID: 32019006
DOI: 10.1016/j.scitotenv.2019.136301

Abstract

The objective of this study was to investigate the color removal in a binary mixture of azo dyes from the photovoltaic electrocoagulation (EC) technique, using spectral deconvolution and the Gaussian fit for qualitative and quantitative determination of the physical color parameter. Initially, a conventional energy source was used to feed the EC reactor and the experimental design was conducted according to the Rotational Central Compound Design (RCCD). The spectral deconvolution method associated to the Gaussian fit aided in the description of the composition of the sample matrix, In the first step, through the Analysis of Variance, the RCCD and the three-dimensional surface response graphs, the optimized operating conditions were identified, which corresponded to 1320 A m^-² with an reaction time of 16.6 min, and an expected removal of 98.40% for Scarlet Red (SR) dye and 1160 A m^-² with a run time of 15.7 min and 97.9% removal for Turquoise Blue (TB) dye. Using the photovoltaic module as the power source of the EC reactor, a maximum removal of 97 ± 0.43% for TB dye and 98% ± 0.81 for SR was obtained. The results encourage the applicability of photovoltaic module-fed EC technology as a promising alternative for the treatment of effluents containing textile dyes, as well as the use of the spectral deconvolution method associated with the Gaussian fit, for the reliability and precision of the results.

Keywords: Azo dye; Color removal; Electrocoagulation; Photovoltaic energy; UV-spectral deconvolution.