Gas-phase 21 Ne NMR studies and the nuclear magnetic dipole moment of neon-21

Włodzimierz Makulski; Piotr Garbacz

doi:10.1002/mrc.5006

Gas-phase ²¹ Ne NMR studies and the nuclear magnetic dipole moment of neon-21

Magn Reson Chem. 2020 Jul;58(7):648-652. doi: 10.1002/mrc.5006. Epub 2020 Feb 24.

Authors

Włodzimierz Makulski¹, Piotr Garbacz¹

Affiliation

¹ Laboratory of NMR Spectroscopy, Faculty of Chemistry, University of Warsaw, Warszawa, Poland.

PMID: 32012333
DOI: 10.1002/mrc.5006

Abstract

Gas-phase ²¹ Ne nuclear magnetic resonance spectra were measured at the natural abundance of ²¹ Ne isotope for samples consisting of pressurized neon up to 60 bar at room temperature and applying the magnetic field of the strength B₀ = 11.7574 T. It showed that the nuclear magnetic resonance frequency is linearly dependent on the density of gaseous neon. The resonance frequency was extrapolated to the zero-density point, and it permitted the determination of the ²¹ Ne nuclear magnetic moment, μ(²¹ Ne) = 0.6617774(10) μ_N . The present value of μ(²¹ Ne) is not influenced by the bulk magnetic susceptibility of neon and interactions between neon atoms; therefore, it is more precise and reliable than the previous result obtained for μ(²¹ Ne).

Keywords: 1H; 21Ne; 21Ne magnetic moment; NMR gas-phase measurements; and 2H NMR spectra.

Publication types

Research Support, Non-U.S. Gov't

Abstract

Publication types

Grants and funding