Supramolecular chemistry has provided versatile and affordable solutions for the design of tough, flexible polymers. However, application of supramolecular chemistry has been limited to the production of rigid, high-performance polymers due to weak segment mobility. This paper describes a new method of toughening rigid high-performance polymers using the synergistic effect between dual Cu2+ -coordination bonds as a crosslink. These dual Cu2+ -coordination cross-linked high-performance polymers are a class of rigid polymers with an outstanding combination of strength and toughness. The distinct lifetimes and binding strengths of the dual Cu2+ -coordination bonds in a rigid polymer network elicit different dynamic behaviors to improve its energy dissipation and mechanical properties. Moreover, the reformation and removal of Cu2+ -coordination bonds by pyrophosphoric acid endows these cross-linked high-performance polymers with recyclability.
Keywords: high-performance polymers; metal-coordination bonds; recyclability; toughening.
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