Enhanced Adsorptive Desulfurization Using Mongolian Anthracite-Based Activated Carbon

Divyam Jha; Mohd Belal Haider; Rakesh Kumar; Narandalai Byamba-Ochir; Wang Geun Shim; Balathanigaimani Marriyappan Sivagnanam; Hee Moon

doi:10.1021/acsomega.9b03432

Enhanced Adsorptive Desulfurization Using Mongolian Anthracite-Based Activated Carbon

ACS Omega. 2019 Nov 25;4(24):20844-20853. doi: 10.1021/acsomega.9b03432. eCollection 2019 Dec 10.

Authors

Divyam Jha¹, Mohd Belal Haider¹, Rakesh Kumar¹, Narandalai Byamba-Ochir², Wang Geun Shim³, Balathanigaimani Marriyappan Sivagnanam¹, Hee Moon⁴

Affiliations

¹ Department of Chemical Engineering, Rajiv Gandhi Institute of Petroleum Technology, Jais 229304, India.
² Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Peace Avenue, Ulaanbaatar 13330, Mongolia.
³ Department of Polymer Science and Engineering, Sunchon National University, Suncheon-si, Jeollanam-do 57922, Republic of Korea.
⁴ School of Chemical Engineering, Chonnam National University, 77 Yongbong-Ro, Buk-Gu, Gwangju 61186, Republic of Korea.

Abstract

This study reports usage of Mongolian anthracite-based porous activated carbons (PMACs), namely, PMAC 1/3 and PMAC 1/4 for model diesel fuel desulfurization, having 500 ppmw of dibenzothiophene (DBT) in n-heptane. Further, the effects of contact time, adsorbent dosage, and temperature on the adsorption capacity were studied systematically. The experimental adsorption isotherm results were well represented by the Sips isotherm for PMAC 1/3 and the dual site Langmuir isotherm for PMAC 1/4. The maximum DBT adsorption by PMAC 1/3 and PMAC 1/4 were 99.7 and 95.7%, respectively. The kinetics for the adsorption of DBT on PMACs follows the pseudo second order behavior. The Weber-Morris plot shows the multilinearity over the entire time range, suggesting that both the surface and pore diffusions control the adsorption. The values of boundary layer thickness for PMAC 1/4 and PMAC 1/3 were found to be 3.183 and 1.643, respectively. Thus, PMAC 1/4 possesses more surface diffusion control than PMAC 1/3. The changes in Gibbs free energy (ΔG°), entropy (ΔS°), and enthalpy (ΔH°) are negative, which confirms that the studied process is spontaneous and exothermic and possesses less randomness at the interface. Based on the Sips isotherm, single-stage batch-adsorber design was prepared for the adsorption of DBT onto PMAC 1/3.