Identification of Odor Active Compounds in Physalis peruviana L

Molecules. 2020 Jan 7;25(2):245. doi: 10.3390/molecules25020245.

Abstract

The volatiles of cape gooseberry fruit (Physalis peruviana L.) were isolated by solvent-assisted flavor evaporation (SAFE), odor active compounds identified by gas chromatography-olfactometry (GC-O) and gas chromatography-mass spectrometry (GC-MS). Quantitation of compounds was performed by headspace-solid phase microextraction (HS-SPME) for all but one. Aroma extract dilution analysis (AEDA) revealed 18 odor active regions, with the highest flavor dilution values (FD = 512) noted for ethyl butanoate and 4-hydroxy-2,5-dimethylfuran-3-one (furaneol). Odor activity values were determined for all 18 compounds and the highest was noted for ethyl butanoate (OAV = 504), followed by linalool, (E)-non-2-enal, (2E,6Z)-nona-2,6-dienal, hexanal, ethyl octanoate, ethyl hexanoate, butane-2,3-dione, and 2-methylpropanal. The main groups of odor active compounds in Physalis peruviana L. were esters and aldehydes. A recombinant experiment confirmed the identification and quantitative results.

Keywords: GC-MS; GC-O; HS-SPME; Physalis peruviana L.; SAFE; aroma; cape gooseberry; flavor; goldenberry; odor-active; sensory analysis.

MeSH terms

  • Acyclic Monoterpenes / analysis
  • Acyclic Monoterpenes / chemistry
  • Aldehydes / chemistry
  • Esters / analysis
  • Flavoring Agents / chemistry*
  • Flavoring Agents / isolation & purification
  • Fruit / chemistry*
  • Furans / analysis
  • Furans / chemistry
  • Gas Chromatography-Mass Spectrometry / methods
  • Odorants / analysis*
  • Olfactometry / methods
  • Physalis / chemistry*
  • Smell / physiology
  • Solid Phase Microextraction / methods
  • Taste / physiology
  • Volatile Organic Compounds / chemistry*
  • Volatile Organic Compounds / isolation & purification

Substances

  • Acyclic Monoterpenes
  • Aldehydes
  • Esters
  • Flavoring Agents
  • Furans
  • Volatile Organic Compounds
  • furaneol
  • linalool