Switchable on-off spin-crossover properties of iron(ii) compounds by trimming intermolecular hydrogen bonds

Na Li; Jin-Peng Xue; Jing-Lin Liu; Yao-Yao Wang; Zi-Shuo Yao; Jun Tao

doi:10.1039/c9dt04685b

Switchable on-off spin-crossover properties of iron(ii) compounds by trimming intermolecular hydrogen bonds

Dalton Trans. 2020 Jan 28;49(4):998-1001. doi: 10.1039/c9dt04685b. Epub 2020 Jan 13.

Authors

Na Li¹, Jin-Peng Xue¹, Jing-Lin Liu¹, Yao-Yao Wang¹, Zi-Shuo Yao¹, Jun Tao¹

Affiliation

¹ Key Laboratory of Cluster Science of Ministry of Education, School of Chemistry and Chemical Engineering, Liangxiang Campus, Beijing Institute of Technology, Beijing 102488, People's Republic of China. taojun@bit.edu.cn zishuoyao@bit.edu.cn.

PMID: 31930274
DOI: 10.1039/c9dt04685b

Abstract

Reversible single crystal-to-single crystal transformations from [FeL₂(NCS)₂]·3MeOH (1·3MeOH, L = 2-(anthracen-10-yl)-1H-imidazo[4,5-f][1,10]phenanthroline) to 1 and 1·2H₂O were reported, which were accompanied by on-off switching of the spin-crossover properties.