Magnetic, Magnetoelastic and Corrosion Resistant Properties of (Fe-Ni)-Based Metallic Glasses for Structural Health Monitoring Applications

Materials (Basel). 2019 Dec 20;13(1):57. doi: 10.3390/ma13010057.

Abstract

We have performed a study of the magnetic, magnetoelastic, and corrosion resistance properties of seven different composition magnetoelastic-resonant platforms. For some applications, such as structural health monitoring, these materials must have not only good magnetomechanical properties, but also a high corrosion resistance. In the fabricated metallic glasses of composition Fe73-xNixCr5Si10B12, the Fe/Ni ratio was varied (Fe+Ni=73% at.) thus changing the magnetic and magnetoelastic properties. A small amount of chromium (Cr5) was added in order to achieve the desired good corrosion resistance. As expected, all the studied properties change with the composition of the samples. Alloys containing a higher amount of Ni than Fe do not show magnetic behavior at room temperature, while iron-rich alloys have demonstrated not only good magnetic properties, but also good magnetoelastic ones, with magnetoelastic coupling coefficient as high as 0.41 for x=0 in the Fe73Ni0Cr5Si10B12 (the sample containing only Fe but not Ni). Concerning corrosion resistance, we have found a continuous degradation of these properties as the Ni content increases in the composition. Thus, the corrosion potential decreases monotonously from 46.74 mV for the x=0, composition Fe73Ni0Cr5Si10B12 to -239.47 mV for the x=73, composition Fe0Ni73Cr5Si10B12.

Keywords: corrosion resistance; electrochemistry; magnetoelastic sensor; magnetoelasticity.