The aim of this work consists on the synthesis of a nanomaterial for heavy metal ion removal from aqueous solutions. Al-doped ZnO (ZnO:Alx%) nanopowders with 0 to 5% Al content are prepared via an amended sol-gel method. The morphology and microstructure of the prepared ZnO:Alx% are probed by means of scanning electron microscopy (SEM), X-ray particles diffraction (XRD) analysis, energy dispersive X-ray spectroscopy (EDS) and elemental mapping. The findings reveal the prevalence of the hexagonal wurtzite ZnO structure with increasing crystallite size (45 to 60 nm) as a result of Al doping. SEM images show nearly spherical nanoparticles with considerable aggregation. EDS and elemental mapping analysis confirm the incorporation of Al within ZnO host lattice. The relatively large surface area as estimated from N2 adsorption makes the nanopowders very favorable for the uptake Cd(II), Cr (IV), Co (II) and Ni(II) from aqueous solution. The ZnO:Alx% with 1 wt% Al exhibits the highest uptake rate of heavy metal ions. The adsorption process has been found to be spontaneous and endothermic and obey Langmuir adsorption model. The high tendency of the prepared nanoparticles to eliminate heavy metal ions renders them suitable candidates for environmental remediation. Desorption studies with 0.1 M NaOH indicate that ZnO:Alx% can be regenerated effectively.
Keywords: Adsorption; Al–ZnO nanopowder; Environmental remediation; Heavy metals removal.