In Situ Metal-Ligand Reactions under Solvent-Dependent Hydro(solvo)thermal Conditions: Structures, Mass Spectrometry, and Magnetism

Ye Tao; Xu-Hong Pang; Hai-Ye Li; He-Dong Bian; Han-Fu Liu; Fu-Ping Huang

doi:10.1021/acs.inorgchem.9b02352

In Situ Metal-Ligand Reactions under Solvent-Dependent Hydro(solvo)thermal Conditions: Structures, Mass Spectrometry, and Magnetism

Inorg Chem. 2020 Jan 6;59(1):308-314. doi: 10.1021/acs.inorgchem.9b02352. Epub 2019 Dec 6.

Authors

Ye Tao¹, Xu-Hong Pang¹, Hai-Ye Li¹, He-Dong Bian², Han-Fu Liu¹, Fu-Ping Huang¹

Affiliations

¹ State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy , Guangxi Normal University , Guilin 541004 , P. R. China.
² Key Laboratory of Development and Application of Forest Chemicals of Guangxi , Guangxi University of Nationalities , Nanning 530006 , P. R. China.

PMID: 31809031
DOI: 10.1021/acs.inorgchem.9b02352

Abstract

In this study, four in situ hydro(solvo)thermal metal-ligand reactions, including oxidation (H₂L¹), C-C coupling (H₄L²), nitration (H₂L³), and condensation (HL^4-6), based on bis[3-(pyridin-2-yl)-1H-1,2,4-triazol-5-yl]methane (H₂L⁰), in the presence of Dy^III ions, were carried out. The in situ metal-ligand reaction gave six new ligands existing in eight novel Dy^III coordination complexes, which were characterized by crystal structure, mass spectrometry, and magnetism.