Polymerization shrinkage and mechanical properties affect the service life of dental restorative composites. Polyhedral oligomeric silsesquioxanes (POSS) can be an efficient strategy to improve the shrinkage properties and mechanical properties simultaneously. In this work, epoxycyclohexyl POSS (E-POSS) was used to modify the Bis-GMA/TEGDMA dental resins. E-POSS were introduced into the acrylic resin system via ring-opening reaction, and a cationic/free radical hybrid system was obtained. Double bond conversion, glass transition temperature, heterogeneity, crosslink density of dental resins and volumetric shrinkage, water sorption/solubility, flexural strength/modulus of dental composites were investigated. As the introduction of E-POSS caused higher double bond conversion and lower crosslink density, the polymerization shrinkage was significantly reduced to 2.91% (p < 0.05) and the flexural strength increased to 117.19 MPa (p < 0.05) compared to the control sample (5.06%, 99.16 MPa, p<0.05). Lower water sorption and solubility were also observed in composites contained E-POSS (p < 0.05).
Keywords: Dental restorative composites; Double initiation system; Low polymerization shrinkage; POSS.
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