This study investigated the occurrence and removals of micropollutants in the sewage treatment tank (STT) which is a typical private wastewater treatment facility used in the rural communities in Korea, and their impact on receiving water. STTs were selected in eight provinces to examine the regional difference in the composition of micropollutant occurrence. We measured ten selected micropollutants in influents and effluents of STTs, as well as upstream and downstream of its receiving surface water. The dominant micropollutants in the influent of the STTs were caffeine (13,346 ng/L), acetaminophen (11,331 ng/L), ibuprofen (1440 ng/L), and naproxen (1313 ng/L), in agreement with the amounts produced annually in Korea. In the effluent, caffeine (1912 ng/L), acetaminophen (1586 ng/L), naproxen (475 ng/L), and ibuprofen (389 ng/L) were detected in relatively high concentrations. The composition of micropollutants in STT influents showed little regional variation by provinces, suggesting that the consumption pattern of these micropollutants did not show regional variation. The removal efficiencies of the selected micropollutants at the STTs ranged from 12% (carbamazepine) to 88% (acetaminophen), lower than typical removal by sewage treatment plants (STPs). This result is probably due to the automatic operation systems and simple treatment processes in STTs compared with STPs. The concentrations of selected micropollutants upstream of the receiving water were generally lower compared with those observed downstream, indicating that effluent from STTs was the main source. The per capita discharge loads of STTs and annual emissions rates (kg/year) from private wastewater treatment facilities were estimated for the selected micropollutants.
Keywords: Endocrine disrupting compounds; Micropollutant; Per capita discharge; Pharmaceuticals; Sewage treatment tank; Wastewater treatment facilities.