The GW approximation to many-body perturbation theory is a reliable tool for describing charged electronic excitations, and it has been successfully applied to a wide range of extended systems for several decades using a plane-wave basis. However, the GW approximation has been used to test limited spectral properties of a limited set of finite systems (e.g., frontier orbital energies of closed-shell sp molecules) only for about a decade using a local-orbital basis. Here, we calculate the quasiparticle spectra of closed- and open-shell molecular anions with partially and completely filled 3d shells (shallow and deep 3d states, respectively), ScO-, TiO-, CuO-, and ZnO-, using various levels of GW theory, and compare them to experiments to evaluate the performance of the GW approximation on the electronic structure of small molecules containing 3d transition metals. We find that the G-only eigenvalue self-consistent GW scheme with W fixed to the PBE level (GnW0@PBE), which gives the best compromise between accuracy and efficiency for solids, also gives good results for both localized (d) and delocalized (sp) states of 3d-transition-metal oxide molecules. The success of GnW0@PBE in predicting electronic excitations in these systems reasonably well is likely due to the fortuitous cancellation effect between the overscreening of the Coulomb interaction by PBE and the underscreening by the neglect of vertex corrections. Together with the absence of the self-consistent field convergence error (e.g., spin contamination in open-shell systems) and the GW multisolution issue, the GnW0@PBE scheme gives the possibility to predict the electronic structure of complex real systems (e.g., molecule-solid and sp-d hybrid systems) accurately and efficiently.