Remote Raman Detection of Chemicals from 1752 m During Afternoon Daylight

Appl Spectrosc. 2020 Feb;74(2):233-240. doi: 10.1177/0003702819875437. Epub 2019 Sep 13.

Abstract

The detection and identification of materials from a distance is highly desirable for applications where accessibility is limited or there are safety concerns. Raman spectroscopy can be performed remotely and provides a very high level of confidence in detection of chemicals through vibrational modes. However, the remote Raman detection of chemicals is challenging because of the very weak nature of Raman signals. Using a remote Raman system, we performed fast remote detection of various solid and liquid chemicals from 1752 m during afternoon hours on a sunny day in Hawaii. Remote Raman systems with kilometer target range could be useful for chemical detection of volcanic gases, methane clathrate icebergs or fire ice, toxic gas clouds and toxic waste, explosives, and hazardous chemicals. With this successful test, we demonstrate the feasibility of developing future mid-size remote Raman systems suitable for long range chemical detection using helicopters and light airplanes.

Keywords: Raman scattering; Remote Raman spectroscopy; active remote sensing; daytime Raman; long range chemical detection; remote chemical detection; remote sensing.