Cr(IV) pollution in water leads to serious environmental contamination and health risks. Among various wastewater treating methods, electrocoagulation (EC) is widely applied because of its high efficiency. However, there is still a problem of high energy consumption that has to be solved by direct current coagulation (DCC). In this paper, a sinusoidal alternating current coagulation (SACC) technique was used to reduce energy consumption and improve the efficiency of Cr(VI) removal. The effects of pH value, current density, initial concentration of Cr(VI) and reaction time are studied on the removal of Cr(VI). The response surface methodology (RSM) was used to optimize the parameters of SACC process. Compared with pulse direct current coagulation (PDCC) and DCC, SACC can greatly reduce the concentration polarization and prevent Fe electrodes from passivation so as to reduce energy consumption and improve the efficiency of Cr(VI) removal. When pH 5.6 wastewater containing 33.1 mg⋅dm-3 Cr(VI) was treated by applying 2.7 A⋅m-2 density for 20.5 min, the removal rate of Cr(VI) reached 99.73%, and the residual Cr(VI) in the effluent was <0.1 mg⋅dm-3. The power consumption of SACC process decreases by 14.98% compared to DCC process and the electrode loss is about 16.4% less than that of the DCC. The coagulation produced by SACC has a large specific surface area and better adsorption performance through analysis of SEM and EDS as well as adsorption dynamic analysis. FTIR and XRD patterns verified the strong interaction between Cr(VI) and iron sol. The Cr(VI) on the electrode can be deposited as a form of insoluble Cr(III) compounds. Langmuir adsorption isotherm model and the second-order kinetic model in SACC are more suitable to explain the adsorption behavior and characteristics of Cr(VI) in SACC.
Keywords: Chromium(VI); Electrocoagulation; Iron electrode; Sinusoidal alternating current (SAC); Wastewater.
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