Synthesis of Nitrogen and Sulfur Codoped Nanoporous Carbons from Algae: Role in CO2 Separation

Dipendu Saha; Ryan Thorpe; Scott E Van Bramer; Nicole Alexander; Dale K Hensley; Gerassimos Orkoulas; Jihua Chen

doi:10.1021/acsomega.8b02892

Synthesis of Nitrogen and Sulfur Codoped Nanoporous Carbons from Algae: Role in CO₂ Separation

ACS Omega. 2018 Dec 27;3(12):18592-18602. doi: 10.1021/acsomega.8b02892. eCollection 2018 Dec 31.

Authors

Dipendu Saha¹, Ryan Thorpe², Scott E Van Bramer¹, Nicole Alexander¹, Dale K Hensley³, Gerassimos Orkoulas¹, Jihua Chen³

Affiliations

¹ Department of Chemical Engineering and Department of Chemistry, Widener University, One University Place, Chester, Pennsylvania 19013, United States.
² Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08854, United States.
³ Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States.

Abstract

Nitrogen and sulfur codoped and completely renewable carbons were synthesized from two types of algae, Spirulina Platensis and Chlorella Vulgaris, without any additional nitrogen fixation reaction. The type of activation agents, char-forming temperature, activation agent-to-char ratio, and activation temperature were all varied to optimize the reaction conditions for this synthesis. The maximum Brunauer-Emmett-Teller surface area and total pore volumes of the carbons were 2685 m²/g and 1.4 cm³/g, respectively. The nitrogen and sulfur contents of the carbons were in the range of 0.9-5.69 at. % and 0.05-0.2 at. %, respectively. The key nitrogen functionalities were pyridinic, amino, and pyridonic/pyrrolic groups, whereas the key sulfur functionalities were S-C, O-S-C, and SO _x groups. CO₂ adsorption isotherms were measured at 273, 298, and 313 K, and the ideal adsorbed solution theory was employed to calculate the selectivity of adsorption of CO₂ over N₂ and simulate binary adsorption isotherms. The adsorption results demonstrated that the CO₂ adsorption amount and the heat of CO₂ adsorption were higher for carbons with higher nitrogen content, confirming the influence of nitrogen functionality in CO₂ adsorption. The overall results suggested that these algae-derived renewable carbons can serve as potential adsorbents for CO₂ separation from N₂.