Understanding Conformational Preferences of Atropisomeric Hydrazides and Its Influence on Excited State Transformations in Crystalline Media

Akila Iyer; Angel Ugrinov; J Sivaguru

doi:10.3390/molecules24163001

Understanding Conformational Preferences of Atropisomeric Hydrazides and Its Influence on Excited State Transformations in Crystalline Media

Molecules. 2019 Aug 19;24(16):3001. doi: 10.3390/molecules24163001.

Authors

Akila Iyer¹, Angel Ugrinov², J Sivaguru³

Affiliations

¹ Center for Photochemical Sciences and Department of Chemistry, Bowling Green State University, Bowling Green, OH 43403, USA.
² Department of Chemistry and Biochemistry, North Dakota State University, Fargo, ND 58108-6050, USA.
³ Center for Photochemical Sciences and Department of Chemistry, Bowling Green State University, Bowling Green, OH 43403, USA. sivagj@bgsu.edu.

Abstract

Hydrazides derivatives were evaluated to understand the role of N-N bond in dictating the outcome of photoreactions in the solid state.

Keywords: asymmetric photochemistry; atropselective photoreactions; chiral photochemistry; hydrazide based photochromophores; photochiral auxiliary; photochirogenesis.

MeSH terms

Heterocyclic Compounds / chemistry*
Molecular Conformation
Organic Chemicals / chemistry*
Photochemistry / methods
Stereoisomerism

Substances

Heterocyclic Compounds
Organic Chemicals

Grants and funding

CHE-1811795/National Science Foundation