Heterochiral recognition among functionalized heptahelicenes on noble metal surfaces

Chem Commun (Camb). 2019 Aug 29;55(71):10595-10598. doi: 10.1039/c9cc05317d.

Abstract

Chiral recognition among three differently functionalized heptahelicene derivatives on Ag(111) and Au(111) surfaces has been studied with scanning tunnelling microscopy. All three species were found to self-assemble into racemic zigzag structures, with alternation of (M)- and (P)-enantiomers.