Chiral superstructures from homochiral Zn2+ , Co2+ , Fe2+ -2,6-bis (aryl ethylimine)pyridine complexes

Abstract

We report the hierarchical supramolecular organization of metallosupramolecular homochiral complexes 1-Λ-(S,S,S,S)-M²⁺ /1-∆-(R,R,R,R)-M²⁺ and 2- Λ-(S,S,S,S)-M²⁺ /2-∆- (R,R,R,R)-M²⁺ of M²⁺ = Co²⁺ , Fe²⁺ , Zn²⁺ metal ions with chiral pseudo-terpyridine-type ligands: 1-(S,S) or 1-(R,R) = 2,6-bis (naphthyl ethylimine)pyridine and 2-(S,S) or 2-(R,R) = 2,6-bis (phenyl-ethylimine)pyridine. Circular dichroism measurements in solution were used to confirm the enantiomeric nature of all twelve complexes. For crystal structures of 1- Λ- (S,S,S,S)-M²⁺ or 1-∆- (R,R,R,R)-M²⁺ complexes, absolute configurations {∆ (or P), Λ (or M)} were confirmed by refinement of the Flack parameter x: -0.007 ≤ x ≤ 0.11 for the single crystals of 1-Λ-(S,S,S,S)-M²⁺ /1-∆- (R,R,R,R)-M²⁺ , 2- Λ- (S,S,S,S)-Fe²⁺ , and 2-∆- (R,R,R,R)-Co²⁺ .

Keywords: aromatic interactions; chiral single crystals; imine; metallosupramolecular complexes; self-assembly.