NMR data for the hydroxyl groups detected by NOESY spectra in sesquiterpene lactones

Jaromir Budzianowski; Joanna Nawrot; Gerard Nowak

doi:10.1016/j.dib.2019.104246

NMR data for the hydroxyl groups detected by NOESY spectra in sesquiterpene lactones

Data Brief. 2019 Jul 12:25:104246. doi: 10.1016/j.dib.2019.104246. eCollection 2019 Aug.

Authors

Jaromir Budzianowski¹, Joanna Nawrot², Gerard Nowak²

Affiliations

¹ Department of Pharmaceutical Botany and Plant Biotechnology, Poznań University of Medical Sciences, Św. Marii Magdaleny Str. 14, 61-861 Poznań, Poland.
² Department of Medicinal and Cosmetic Natural Products, Poznań University of Medical Sciences, Mazowiecka Str. 33, 60-623 Poznań, Poland.

Abstract

In this article we present the correlations observed in the NOESY spectra, which provide direct and unequivocal detection of hydroxyl groups occurring in the chemical structures of three sesquiterpene lactones - a germacranolide (8α-(E)-4'-hydroxysenecioyloxy-9α-hydroxyparthenolide) and two guaianolides (cynaropicrin and desacylcynaropicrin 8α-(Z)-(4'-hydroxy-2'-methyl)butenoate). The NOESY spectra and other NMR spectra, which served for the structural determination, are also presented. The data provided in this article are associated with the research article "Phytochemical profiles of the leaves of Stizolophus balsamita and Psephellus sibiricus and their chemotaxonomic implications" Nawrot et al., 2019.

Keywords: Hydroxyl groups detection; NMR spectra; NOESY spectra; Sesquiterpene lactones.