A novel mesoporous biochar (PBC) was facilely prepared from Medulla tetrapanacis. PBC exhibited high efficiency for the sorption of Cu2+ (458.72 mg/g) and Pb2+ (1031.23 mg/g) ions, and these values were higher than that of reported literatures. In the multi-metal system, the maximum sorption capacity for Cu2+, Pb2+, Cr3+, and Fe3+ were 430.88 mg/g, 701.63 mg/g, 696.67 mg/g, and 697.01 mg/g, respectively, and the removal efficiencies of those ions were more than 80% at a metal ion concentration of 200 mg/L. Furthermore, the PBC was effective for the treatment of industrial effluent wastewater. The ash content (45.46%) of the PBC was higher than that of most other biochar derived from lignocellulosic biomass. Complexation, precipitation, π-π interactions, ion exchange, and physical sorption were the main sorption mechanisms. Overall, PBC is an inexpensive product, which is simply synthesized and an excellent adsorbent for heavy metal ion removal.
Keywords: Low density; Medulla tetrapanacis; Multi-metal sorption; Sorption mechanism.
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