Operando X-ray absorption spectra and mass spectrometry data during hydrogenation of ethylene over palladium nanoparticles

Aram L Bugaev; Alexander A Guda; Ilia A Pankin; Elena Groppo; Riccardo Pellegrini; Alessandro Longo; Alexander V Soldatov; Carlo Lamberti

doi:10.1016/j.dib.2019.103954

Operando X-ray absorption spectra and mass spectrometry data during hydrogenation of ethylene over palladium nanoparticles

Data Brief. 2019 Apr 26:24:103954. doi: 10.1016/j.dib.2019.103954. eCollection 2019 Jun.

Authors

Aram L Bugaev¹, Alexander A Guda¹, Ilia A Pankin^{1

2}, Elena Groppo², Riccardo Pellegrini³, Alessandro Longo^{4

5}, Alexander V Soldatov¹, Carlo Lamberti^{1

6}

Affiliations

¹ The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russia.
² Department of Chemistry, INSTM and NIS Centre, University of Turin, Via Quarello 15, 10125 Turin, Italy.
³ Chimet SpA - Catalyst Division, Via di Pescaiola 74, Viciomaggio Arezzo, 52041 Italy.
⁴ Netherlands Organization for Scientific Research at ESRF, BP 220, F-38043 Grenoble Cedex 9, France.
⁵ Istituto per Lo Studio Dei Materiali Nanostrutturati (ISMN)-CNR, UOS Via Ugo La Malfa, 153, 90146 Palermo, Italy.
⁶ Department of Physics and CrisDi Interdepartmental Centre, University of Turin, Via P. Giuria 1, 10125 Turin, Italy.

Abstract

We report the series of Pd K-edge X-ray absorption spectra collected during hydrogenation of ethylene with variable ethylene/hydrogen ratio over carbon supported palladium nanoparticles. The data presented in this article includes normalized X-ray absorption spectra, k ²-weighted oscillatory χ(k) functions extracted from the extended X-ray absorption fine structure (EXAFS) and k ²-weighted Fourier-transformed EXAFS data, χ(R). Each spectrum is reported together with the hydrogen, ethylene and helium flow rates, adjusted during its collection. In addition, time evolution of the ratio of m/Z signals of 30 and 28 registered by online mass spectrometer is presented. The data analysis is reported in Bugaev et al., Catal. Today, 2019 [1].