Ionothermal Synthesis of Crystalline Nanoporous Silicon and Its Use as Anode Materials in Lithium-Ion Batteries

Fei Wang; Baoxun Zhao; Wenwen Zi; Hongbin Du

doi:10.1186/s11671-019-3024-9

Ionothermal Synthesis of Crystalline Nanoporous Silicon and Its Use as Anode Materials in Lithium-Ion Batteries

Nanoscale Res Lett. 2019 Jun 6;14(1):196. doi: 10.1186/s11671-019-3024-9.

Authors

Fei Wang¹, Baoxun Zhao¹, Wenwen Zi¹, Hongbin Du²

Affiliations

¹ State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.
² State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China. hbdu@nju.edu.cn.

Abstract

Silicon has great potential as an anode material for high-performance lithium-ion batteries (LIBs). This work reports a facile, high-yield, and scalable approach to prepare nanoporous silicon, in which commercial magnesium silicide (Mg₂Si) reacted with the acidic ionic liquid at 100 °C and ambient pressure. The obtained silicon consists of a crystalline, porous structure with a BET surface area of 450 m²/g and pore size of 1.27 nm. When coated with the nitrogen-doped carbon layer and applied as LIB anode, the obtained nanoporous silicon-carbon composites exhibit a high initial Coulombic efficiency of 72.9% and possess a specific capacity of 1000 mA h g^-1 at 1 A g^-1 after 100 cycles. This preparation method does not involve high temperature and pressure vessels and can be easily applied for mass production of nanoporous silicon materials for lithium-ion battery or for other applications.

Keywords: Anode material; Lithium-ion battery; Nanomaterial; Silicon.