Incorporation of Brazilian Diatomite in the Synthesis of An MFI Zeolite

Molecules. 2019 May 23;24(10):1980. doi: 10.3390/molecules24101980.

Abstract

The need for greener procedures is a fact to reduce residues, to decrease industrial costs, and to accomplish the environmental agreements. In an attempt to address this question, we propose the addition of a natural resource, Brazilian diatomite, to an MFI zeolite traditional synthesis. We have characterized the resulting product with different techniques, such as X-ray diffraction, microscopy, and gas sorption, and, afterwards, we evaluate the greenness of the process by the Green Star method. The results were promising: We obtained the desired topology in the form of small crystallites aggregated and a pore diameter of 0.8 nm. In conclusion, the product has the necessary characteristics for an adsorption or catalytic future tests and escalation to industrial production.

Keywords: MFI zeolite; alternative sources; diatomite; microporous material.

MeSH terms

  • Brazil
  • Diatomaceous Earth / chemistry*
  • Green Chemistry Technology
  • Models, Molecular
  • Surface Properties
  • X-Ray Diffraction
  • Zeolites / chemical synthesis*
  • Zeolites / chemistry

Substances

  • Zeolites
  • Diatomaceous Earth
  • diatomite