In this study, a transition-metal selenide, vanadium diselenide (VSe2), with various morphologies was synthesized by employing a surfactant-free hydrothermal method under varied temperature conditions (190-220 °C). Although the physical properties of VSe2 have been studied before, only limited morphological change or application were explored. This study, for the first time, applied VSe2 as the electrocatalytic counter electrode (CE) in dye-sensitized solar cells (DSSCs) and showed an attractive cell efficiency. The mechanism of forming the tunable VSe2 morphologies is proposed. The evaluation of solar cell efficiency shows the correlation between morphology and electrocatalytic properties. It was further shown that VSe2-200 with the cauliflower-like morphology shows the highest cell performance of DSSC with an efficiency of 9.23 ± 0.07% under 1 sun irradiance, superior to that of the Pt-based DSSC (8.48 ± 0.08%). An electrochemical technique equipped with a rotating disk electrode system was introduced to confirm the high electrocatalytic performance with this particular morphology. The optimized VSe2 demonstrated good long-term stability with 78% retention after 500 cycles of the consecutive cyclic voltammetry, compared to 60% for the Pt CE. The control in morphology in vanadium diselenide synthesis and its usage in Pt-free CE DSSC have advanced the progress in electrochemistry.
Keywords: Pt-free electrocatalyst; counter electrode; dye-sensitized solar cell; morphology; rotating disk electrode; vanadium diselenide.