The presence of nitroarenes formed by secondary atmospheric processes in the Japanese freshwater environment

Abstract

In this study, the concentrations and distributions of nitrated polycyclic aromatic hydrocarbons (NPAHs) were characterized in the freshwater environment of a Japanese city. While the NPAHs were few in number, they were found in pg/L concentrations and the specific isomers suggested the deposition of NPAHs formed via the atmospheric transformation of PAHs. The absence of NPAHs formed via primary combustion processes such as automobile exhaust, suggests that improvements in emission standards are being reflected in the environment, though the NPAHs formed by secondary atmospheric processes are still a significant ecotoxicological threat. The stability of the NPAHs was also examined in spiked freshwater matrices. There was a significant decrease in spiked NPAHs over this period, suggesting that they were either being sorbed or transformed and are therefore not long lived in the freshwater environment. This indicates that the NPAHs found in freshwater samples are from recent deposition.

Keywords: Aquatic toxicology; Nitrated polycyclic aromatic hydrocarbons; PAH transformation; Water pollution.