Synthesis of a Carbonaceous Two-Dimensional Material

ACS Appl Mater Interfaces. 2019 Jun 19;11(24):21308-21313. doi: 10.1021/acsami.9b01808. Epub 2019 Apr 26.

Abstract

Despite tremendous accomplishments achieved in 2D materials, little progress has been made in carbonaceous 2D materials beyond graphene and graphene oxide. Here, we report a 2D material of carbonaceous nanoplates (CANP). The bottom-up synthesis of CANP is green, separation-free, and massive. The nanoplates are 2 to 3 monolayers thick with an average interlayer spacing of 0.57 nm. The synthesis involves viscosity-aided two-dimensional growth of fragmented glucose derivatives and leads to the complete conversion of glucose to the 2D nanoplates. Application tests demonstrate the usefulness of the affordable 2D material.

Keywords: carbonaceous plates; furan-arene oxide; hydrothermal process; two-dimensional growth; two-dimensional materials.