Biosourced Binder for Wood Particleboards Based on Spent Sulfite Liquor and Wheat Flour

Polymers (Basel). 2018 Sep 27;10(10):1070. doi: 10.3390/polym10101070.

Abstract

Currently, the majority of binders used in wood particleboard (PB) manufacturing are formaldehyde-based synthetic resins. Because of the toxicity of formaldehyde, there is a strong demand for eco-friendly alternatives with similar performances and economic viability. In this work, thick spent sulfite liquor (TSSL), an industrial byproduct from sulfite pulp mills, is proposed as a binder for fully bio-based PBs. The results showed that PBs bound with TSSL present appropriate mechanical performance, which was further improved when TSSL was combined with wheat flour at an 84:16 dry weight ratio and preheated to 94 °C prior to application. For 13.2% binder content per dry wood weight, the PB internal bond strength was 0.46 N mm-2, which is above the standard requirements for PB type P2 (0.35 N mm-2). Optical microscopy showed that TSSL hinders the gelatinization of starch granules during preheating, allowing the binder mixture to maintain a low viscosity suitable for combination with wood particles and PB production.

Keywords: bioadhesives; spent sulfite liquor; wheat flour; wood composites.