Latent fingermark detection using functionalised silicon oxide nanoparticles: Method optimisation and evaluation

Po Lun Timothy Lee; Fehmida K Kanodarwala; Chris Lennard; Xanthe Spindler; Val Spikmans; Claude Roux; Sébastien Moret

doi:10.1016/j.forsciint.2019.02.038

Latent fingermark detection using functionalised silicon oxide nanoparticles: Method optimisation and evaluation

Forensic Sci Int. 2019 May:298:372-383. doi: 10.1016/j.forsciint.2019.02.038. Epub 2019 Mar 14.

Authors

Po Lun Timothy Lee¹, Fehmida K Kanodarwala², Chris Lennard³, Xanthe Spindler², Val Spikmans³, Claude Roux², Sébastien Moret²

Affiliations

¹ Western Sydney University, School of Science and Health, Richmond, NSW, 2753, Australia. Electronic address: timothy.lee@westernsydney.edu.au.
² University of Technology Sydney, Centre for Forensic Science, Broadway, NSW, 2007, Australia.
³ Western Sydney University, School of Science and Health, Richmond, NSW, 2753, Australia.

PMID: 30928777
DOI: 10.1016/j.forsciint.2019.02.038

Abstract

The application of nanoparticles for latent fingermark detection has been reported in the literature over the past two decades. One of the nanoparticles that shows promise to become a routine technique is functionalised silicon oxide nanoparticles (SiO₂ NPs). In a recent optimisation of the technique, the use of carboxyl-functionalised SiO₂ NPs doped with luminescent ruthenium complex was proposed as a breakthrough for latent fingermark detection. In this study, the aforementioned functionalised SiO₂ NPs were extensively evaluated. Modification and optimisation of the original detection parameters were performed to enhance detection quality and improve applicability. Various detection parameters were evaluated and assessed. A lower concentration of the functionalised nanoparticles used in the colloidal dispersion was determined to offer improved detection effectiveness. A combination of increased bath temperature and reduced immersion time was found to produce good overall results. A set of modified detection parameters was suggested for the use of the functionalised SiO₂ NPs to detect latent fingermarks. Performance of the modified detection parameters was compared against that of the published detection method. Comparison experiments were carried out on fingermark specimens deposited on aluminium foil, transparent polypropylene plastic and green polyethylene plastic. Three donors (weak, average and strong) and two age intervals (ten days and three months) were considered in the comparison study. Evaluation of the results suggested that the overall performance of the modified method for latent fingermark detection was superior to that obtained using the previously published detection parameters.

Keywords: Bath temperature; Colloidal; Detection effectiveness; Luminescence technique; Method modification; Surface functionalisation.