Enhancing photocatalytic degradation of methyl orange by crystallinity transformation of titanium dioxide: A kinetic study

Abstract

This work aimed to enhance the photocatalytic degradation of methyl orange (MO) by crystallinity transformation of titanium dioxide (TiO₂ ). In addition, the kinetic degradation of MO was determined. To transform its crystallinity, TiO₂ was synthesized using a sol-gel method and calcined at between 200°C to 600°C. Calcination at a temperature of 250°C resulted in TiO₂ that showed the best performance, corresponding to MO removal of 87% ± 7%. MO removal by TiO₂ calcined between 250°C to 400°C was higher than for commercial TiO₂ powder (Sigma-aldrich) (62% ± 4%). TiO₂ with a small crystallite size and high anatase fraction enhanced the photocatalytic degradation of MO, while the specific surface area and surface roughness seemed to play a minor role. The photocatalytic degradation of MO was NaCl-independent, while the photocatalytic activity increased with decreased pH. Reused TiO₂ showed similar photocatalytic degradation of MO compared with pristine TiO₂ , at 84 ± 2%. The oxidation kinetics of TiO₂ calcined at 250°C were fitted to the Langmuir-Hinshelwood model (R² = 0.9134). The k_r and K_s values were 0.027 mg L^-1 min^-1 and 0.621 L/mg, respectively. Crystallinity transformation was a major factor in the enhancement of photocatalytic degradation of MO. PRACTITIONER POINTS: Photocatalytic activity of TiO₂ depends on calcination temperature, pH, and a number of UVC lamps. TiO₂ with a small crystallite size and high anatase fraction enhanced the photocatalytic degradation of MO.

Keywords: crystallinity; kinetics; methyl orange; photocatalyst; titanium dioxide.