Clear and transparent nanocrystals for infrared-responsive carrier transfer

Nat Commun. 2019 Jan 24;10(1):406. doi: 10.1038/s41467-018-08226-2.

Abstract

Infrared-light-induced carrier transfer is a key technology for 'invisible' optical devices for information communication systems and energy devices. However, clear and colourless photo-induced carrier transfer has not yet been demonstrated in the field of photochemistry, to the best of our knowledge. Here, we resolve this problem by employing short-wavelength-infrared (1400-4000 nm) localized surface plasmon resonance-induced electron injection from indium tin oxide nanocrystals to transparent metal oxides. The time-resolved infrared measurements visualize the dynamics of the carrier in this invisible system. Selective excitation of localized surface plasmon resonances causes hot electron injection with high efficiency (33%) and long-lived charge separation (~ 2-200 μs). We anticipate our study not only provides a breakthrough for plasmonic carrier transfer systems but may also stimulate the invention of state-of-the-art invisible optical devices.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Infrared Rays*
  • Kinetics
  • Microscopy, Electron, Transmission
  • Nanoparticles / chemistry*
  • Nanoparticles / radiation effects*
  • Particle Size
  • Photochemistry*
  • Physical Phenomena
  • Silicon Dioxide / chemistry
  • Spectroscopy, Near-Infrared
  • Surface Plasmon Resonance*
  • Surface Properties
  • Tin Compounds / chemistry*
  • Tin Compounds / radiation effects*

Substances

  • Tin Compounds
  • indium tin oxide
  • Silicon Dioxide