Effect of Ce Addition on Modifying the Microstructure and Achieving a High Elongation with a Relatively High Strength of As-Extruded AZ80 Magnesium Alloy

Materials (Basel). 2018 Dec 26;12(1):76. doi: 10.3390/ma12010076.

Abstract

Forming magnesium alloys with rare earth elements (La, Gd, Nd, Y, Ce) is a routine method for modifying their microstructure and properties. In the present work, the effect of Ce addition on the microstructure evolution and the mechanical properties of as-extruded Mg-8Al-0.5Zn (AZ80) alloy was investigated. All of the extruded AZ80-xCe (x = 0, 0.2, 0.8 and 1.4 wt %) alloys exhibited equiaxed grains formed by fully dynamic recrystallization, and the grain size of the extruded AZ80 alloy was remarkably reduced by ~56.7% with the addition of 1.4 wt % Ce. Furthermore, the bulk-shaped Al₄Ce phase formed when Ce was first added, with the Ce content rising to 0.8 wt % or higher, and Al₄Ce particles in both the nano- and micron sizees were well distributed in the primary α-Mg matrix. The area fraction of the Al₄Ce particles expanded with increasing Ce content, providing more nuclei for dynamic recrystallization, which could contribute to the grain refinement. The results of the tensile tests in this study showed that Ce addition effectively improved the room temperature formability of the as-extruded AZ80 alloy, without sacrificing strength. The significantly improved mechanical properties were ascribed to excellent grain refinement, weakened texture strength, an increased Schmid factor, and a reduced area fraction of low-angle grain boundaries, all resulting from Ce addition to the as-extruded AZ80 alloy. The contribution of the nano-Al₄Ce precipitates on improving the mechanical properties was also discussed in this paper.

Keywords: AZ80 magnesium alloy; Ce modification; elongation; extrusion; microstructure; strength.