Temperature-Controlled Degree of Interpenetration in a Single-Crystal-to-Single-Crystal Transformation within Two Co(II)-Triazole Frameworks

Inorg Chem. 2019 Jan 7;58(1):18-21. doi: 10.1021/acs.inorgchem.8b01339. Epub 2018 Dec 17.

Abstract

Four-fold interpenetrating framework 1a can be constructed driven by temperature-controlled SC-SC transformation from 2-fold interpenetrating network 1. Luminescent properties indicated that 1a can be viewed as a luminescent sensor of high-explosives.